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Covalent Bonding Covalent bonding is based on cooperative sharing of valence electrons. It can be described by orbital overlap. Covalent bonds are conspicuously directional: The bond is manifest in the direction of the greatest orbital overlap. The potential energy of a system of covalently interacting atoms depends not only on the type of atoms and the distances between atoms but also on the physical angles between bonds. The covalent bond model asserts that an atom can covalently bond with at most 8 n , where n is the number of valence electrons. Compounds that are formed due to covalent bonding of atoms are called covalent compounds. See Figure 3.2, middle. Covalent bonds are generally formed between nonmetals. Nitrogen gas (N2), hydrogen gas (H2), oxygen gas (O2), and hydrochloric acid (HCl) represent some of the examples of covalent bonded compounds. Most of the carbon bonds in organic materials (cells, sugar, etc.) are examples of covalent bonds. Since covalent bonds are directional in space, the molecules that arise have de nite shapes. The physical length of covalent bonds (distance between the atoms forming the respective bonds) is shorter than the length of an ionic bond. It follows that covalent bonds are harder to break compared with ionic bonds. Due to the absence of free ions, covalent compounds are not good conductors of heat and electricity. The characteristics

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where the rst and third rows are the linear terms, and the second row is the nonlinear term truncated to the second power. We now try to split eq. (1.59) into several simpler equations. The terms in this equation depend on time through exponential terms at different frequencies. In order that their sum be zero for all time instants t, all terms depending on time with the same frequency must sum up to zero because of the orthogonality of the sinusoidal functions with respect to time. We can therefore equate the sums of all the terms at the same frequency to zero: C j 1 H1 ( 1 ) ej 1 t + g1 H1 ( 1 ) ej 1 t + is ej 1 t = 0 C j 2 1 H2 ( 1 , 1 ) e

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5.2.1 Polyacrylamide Nondenaturing Electrophoresis The gel network formed by polyacrylamide is a suitable environment for the electrophoretic separation of proteins in their native state, that is under nondenaturing conditions. In such conditions, the protein is regarded as being in its intact fully-active form with the correct secondary, tertiary and quaternary structure. It separates on the basis of intrinsic charges on amino acid side-chains and other groups located on the protein surface. Since the precise number and strength of positive and negative charges will vary from protein to protein, each will have a characteristic mobility in a nondenaturing system determined by a combination of these charges together with physical characteristics of the protein such as mass and shape.

12.6.1 Air flow Figure 12.4 shows a detailed comparison of the CFD predictions and measurements of air velocity magnitude on an axial traverse taken between the wafters and the end winding. This

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As supplied to the primary textile industry, synthetic bers contain several types of impurities, including nishes (e.g., antistatic, lubricants), synthesis by-products (e.g., monomer, oligomer, catalyst), additives (e.g., antistatic, lubricant, humectant), delusterants, and uorescent brighteners. These can vaporize or wash off during wet processing operations, producing aquatic and air pollution, toxicity, metals contamination of wastewater and treatment sludges, BOD, COD, and TOC. Tests of wastewater ef uent from mills that exhibited aquatic toxicity identi ed many speci c ber contaminants [40, 45]. Fiber extracts also exhibited high BOD and COD, as shown in Table 7.23. Note that the COD:BOD ratio of the acrylic extract was very high, indicating the potential for pass-through during treatment and subsequent discharge to the environment. Speci c compounds shown in Table 7.24 have been identi ed in synthetic ber extracts. Many of these are undesirable in wastewater or are VOCs. Metals extracted from synthetic bers are shown in Table 7.25 [45].

shrinkage in their 401(k) retirement plans to get the chills particularly if those plans included stock in Enron and WorldCom. Americans expect charities to do good work. They may still buy Asian-stitched jeans from Levi Strauss, wash them with Ivory Snow, and drive to the store in a restored Pinto, but they ll never give to you again if jilted. It s this growing, cynical donor base that will lose its trust of charities quickly if the organizations don t follow ethical rules online. It s estimated that roughly $2 billion was donated online last year. That s a spit in the ocean of $240 billion donated to charity during 2003. The authors of this book learned from the technology bust of the middle-1990s. Instead of technology being the be-all and end-all, they explain that it s just one element of fundraising. Finally, common sense prevails. Paul Clolery Vice President/Editorial Director NPT Publishing Group/The NonProfit Times

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